Thermal Stability and Phase Transformations of Multicomponent Iron-Based Amorphous Alloys

Due to their excellent functional properties enabling their applicability in different fields of modern technology, amorphous alloys (metallic glasses) based on iron have been attracting attention of many scientists. In this chapter, the results of mul-tidisciplinary research of five multicomponent iron-based amorphous alloys with different chemical composition, Fe 81 Si 4 B 13 C 2 , Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 , Fe 75 Ni 2 Si 8 B 13 C 2 , Fe 73.5 Cu 1 Nb 3 Si 15.5 B 7 , and Fe 40 Ni 40 P 14 B 6 , are summarized in order to study the influence of chemical composition on their physicochemical properties and functional-ity. The research involved thermal stability, mechanism, thermodynamics, and kinetics of microstructural transformations induced by thermal treatment and their influence on functional properties. Determination of crystallization kinetic triplets of individual phases formed in the alloys is also included. The results obtained for different alloys are compared, correlated, and discussed in terms of the alloy composition and microstructure. A detailed study of five iron-based amorphous alloys with the compositions Fe Si 4 B 13 C 2 , Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 , Fe 75 Ni 2 Si B 13 C 2 , Fe 73.5 Cu 1 Nb 3 Si 15.5 B 7 , and Fe 40 Ni 40 P 14 B 6 revealed that the alloy behavior in terms of mechanism, thermodynamics, and kinetics of thermally induced microstructural transformations, as well as the functional properties, is significantly influenced by chemical composition of the alloy. The highest thermal stability among the studied alloys was observed for the Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 alloy due to its optimal chemical composition. Crystallization changed alloy microstructure and morphology, making the alloys grainy and more porous, influencing the functional properties of the alloys. Crystalline α -Fe(Si) and Fe 2 B phases were observed to be the final crystallization products in all the alloys with Fe as the dominant component. Kinetic analysis of individual crystallization steps, performed after peak deconvolution, revealed around 25% lower apparent activation energy values of the Fe 2 B phase than those of the α -Fe(Si) phase, for most of the studied alloys, as a result of promoted Fe 2 B crystallization by formation of α -Fe(Si) grains and an enrichment of the amorphous matrix with boron. Relatively high stability of the studied alloys against crystallization was observed at room temperature in spite of thermodynamic metastability and kinetic metastability of amorphous materials, with its abrupt drop at increased temperatures.


Introduction
Amorphous alloys (metallic glasses), composed of metallic and metalloid elements, characterized by a short-range atomic ordering, have been attracting a lot of scientific attention because of their extraordinary isotropic physical and mechanical properties [1][2][3]. Within this class of materials, the iron-based alloys stand out by a unique combination of magnetic, electrical, mechanical, and anticorrosion properties, which makes them suitable for many applications, as multifunctional materials [3][4][5]. Their applications as soft magnetic materials are mainly based on their low coercivity, high permeability, high saturation induction, low eddy current losses, low magnetic reversal losses, and high Curie temperature [6,7]. Due to their high strength and hardness, large elastic elongation limit, and good corrosion resistance, amorphous alloys are convenient for different structural applications [3,8]. Their functional properties as well as their thermal stability can be tuned by an appropriate choice of alloying elements. It is considered that the glass-forming ability of the alloy is improved if empirical component rules [9,10] are fulfilled:
X-ray diffraction (XRD) measurements were performed in Bragg-Brentano geometry, using a Co K α radiation source, at room temperature. Preparation of thermally treated samples included isothermal annealing of the alloy samples sealed in a quartz ampoule at selected temperatures, for 60 min in the case of the Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 alloy and for 30 min for all the other alloys. Qualitative and quantitative analyses of the collected XRD data of the as-prepared and thermally treated samples were conducted using ICSD [31], PDF-2 [32], and COD [33] databases and Maud [34] software.
Transmission electron microscopy (TEM) images were recorded with a Philips CM12 microscope (tungsten cathode, 120 kV electron beam). For TEM measurements, samples were prepared using the focused-ion beam (FIB) method (Ga ions). JEOL JSM 6460 was used to collect scanning electron microscopy (SEM) images.
Thermal analyses of the studied alloys were carried out by means of differential scanning calorimetry (DSC) in a protective nitrogen or helium atmosphere, at constant heating rates. Complex crystallization peaks were deconvoluted [19,[21][22][23][24] Thermal Stability and Phase Transformations of Multicomponent Iron-Based Amorphous Alloys DOI: http://dx.doi.org /10.5772/intechopen.88260 using either Gaussian-Lorentzian cross-product function or Fraser-Suzuki function, taking into consideration the criteria related to the nature of the process as well as the mathematical criteria.
Thermomagnetic measurements were conducted in an evacuated furnace using an EG&G vibrating sample magnetometer, under magnetic field of 4 kA m −1 , at constant heating rate. Electrical resistivity measurements were performed by the four-point method, in an inert atmosphere. Vickers microhardness was determined using MHT-10 (Anton Paar, Austria) microhardness testing device, with 0.4 N loads and 10 s loading time.

Results and discussion
Considering the metastability of amorphous alloys, preservation of microstructure and knowledge of thermal stability in wide temperature range are crucial for their practical applications. In this sense, our investigations start by structural characterization of several as-prepared Fe-based amorphous alloys of different chemical compositions, followed by thermal analysis.

Structural characterization of the as-prepared alloys
In order to obtain detailed information on microstructure of the as-prepared alloys and the nature of individual crystallization steps, the XRD and Mössbauer spectroscopy methods were applied [15,20,25,28,30]. The XRD results revealed that the microstructure of the as-prepared alloys is characterized by short-range atomic ordering showing characteristic broad diffraction halo maxima. According to the positions of broad diffraction halo maxima (2θ = 52 and 96°, Figure 1), the starting atomic configuration corresponds to the bcc-Fe structure, for all the studied alloys. Short-range ordering domain sizes for all the alloys were estimated to be approximately 1.6 nm according to the Scherrer equation [35].
Nevertheless, the as-prepared structures of the Fe 73.5 Cu 1 Nb 3 Si 15.5 B 7 and Fe 81 B 13 Si 4 C 2 alloys are not completely amorphous, containing certain amounts of crystalline phases. Based on the sharp maximum in the XRD diagram (Figure 1) and the results of Mössbauer spectroscopy [28], 5% of the structure of the as-prepared Fe 81 B 13 Si 4 C 2 alloy is in crystalline form. This can be caused by high Fe content in this alloy and the fact that it does not contain any metal element other than Fe, so the requirements for easier amorphization [11] are not fully met. On the other hand, according to Mössbauer spectroscopy [20], 3.5% of the structure of the as-prepared Fe 73.5 Cu 1 Nb 3 Si 15.5 B 7 alloy correspond to crystalline clusters and disappear on heating, during the process of structural relaxation. This amount of crystalline phase is very close to the lowest amount which could be detected by XRD and consequently was not noticed in the XRD patterns (Figure 1). The appearance of crystallinity in this case was contributed by the presence of Cu atoms, which, when present in small amounts, form clusters serving as precursors for nucleation of the α-Fe(Si) crystalline phase.

Thermal stability of the alloys
According to the results of thermal analysis, all of the studied alloys possess good thermal stability at temperature under 380°C (Figure 2a). The glass transition preceding crystallization can be clearly observed only for the Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 and Fe 81 B 13 Si 4 C 2 alloys (Figure 2b), suggesting their higher glass-forming ability than those of the other alloys studied. By applying DSC method, correlation between thermal stability of the alloys and their chemical composition was observed. The lowest thermal stability was demonstrated by the alloy with lower content of iron, Fe 40 Ni 40 P 14 B 6 , containing P instead of Si, with the beginning of crystallization at round 380°C. The alloys with higher content of iron show higher thermal stability, where the alloys Fe 73.5 Cu 1 Nb 3 Si 15.5 B 7 , Fe 75 Ni 2 Si 8 B 13 C 2 , and Fe 81 B 13 Si 4 C 2 begin to crystallize at around 500°C and Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 even at around 520°C. The temperatures corresponding to the start of crystallization observed for the examined alloys ( Table 1) are in agreement with the literature data for the similar systems [36]. A somewhat higher thermal stability of the Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 alloy was also suggested by a wide temperature range corresponding to supercooled liquid region (Figure 2b). This behavior results from the optimal chemical composition including two metal elements with the total content of around 80% (at.) and three nonmetallic amorphizers with the total content of around 20%.
The peak shape of exothermal stabilization maxima, sharp or rounded in some degree, and the presence of more than one maximum (Figure 2) indicate the occurrence of several parallel or consecutive steps of thermal stabilization, for all the studied alloys [19,[21][22][23][24]. The alloys containing higher amount of iron (Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 and Fe 81 B 13 Si 4 C 2 ) exhibit one well-defined sharp crystallization peak, while the alloys with slightly lower amount of iron (Fe 73.5 Cu 1 Nb 3 Si 15.5 B 7 and Fe 75 Ni 2 Si 8 B 13 C 2 ) show two distinct completely separated compounded peaks (Figure 2a), which correspond to different crystallization and recrystallization steps. The alloy containing equal amounts of Fe and Ni (40% at.) exhibits two (one compounded and one sharp) partially overlapped DSC peaks, pointing out several crystallization steps.
The enthalpies of different crystallization steps for all the alloys are determined from the area corresponding to DSC peaks at various heating rates. Various heating rates yield different enthalpy values, showing that thermal history of a sample has a significant impact on the final state of the system. The starting state of the system is the same, but the final state is influenced by duration of thermal treatment as well as by the temperature, influencing the value of determined enthalpies. The observed average absolute values of the enthalpies at heating rates 5-20°C min −1 ( Table 1) for crystallization are 80-110 J/g, but for recrystallization are around 20 J/g.

Thermally induced structural transformations
For more information on thermally induced microstructural transformation of the alloys and the nature of individual crystallization steps, the XRD, Mössbauer spectroscopy, and SEM and TEM methods were applied on the alloy samples isothermally treated at different temperatures, chosen according to the DSC thermograms.
With thermal treatment of the alloys, new narrow peaks appear in the XRD diffractograms as a result of crystallization. The changes of their relative intensities and areas point out the changes in microstructural parameters of the formed phases provoked by thermal treatment at different temperatures. The appearance and disappearance of some sharp peaks in the XRD patterns with a rise in temperature of thermal treatment indicate the processes of recrystallization and formation of one phase at the expense of another [15,18,20,26,30]. The analysis of the obtained XRD patterns yielded the information about microstructure of the studied samples and the phase composition diagrams (Figure 3, Table 2).
Due to the presence of bcc-Fe-like atomic configuration in the ordered domains of the as-prepared alloys, the α-Fe(Si) phase is the first crystalline phase formed in amorphous matrix during thermal treatment of the alloys [15,18,20,26,30].  For these alloys, the beginning of crystallization of the α-Fe(Si) phase from the amorphous structure is observed at approximately the same temperatures (around 450-500°C), with the exception of the Fe 40 Ni 40 P 14 B 6 alloy containing the lowest amount of iron (380°C). This phase remains the dominant crystalline phase over the whole temperature range examined. Formation of the α-Fe(Si) phase is also contributed by a tendency toward creation of stronger bonds between Fe and Si than between Fe and B, and repulsion between Si and B, as indicated by ab initio molecular dynamic simulations [37]. Crystallization of the α-Fe(Si) phase brings about favorable conditions for crystallization of boride phases, since in amorphous matrix, in the vicinity of  , which contains 7 atomic % of boron, the metastable Fe 3 B phase is observed only using Mössbauer spectroscopy and in lower amount than in the alloys containing higher quantity of boron [20]. Upon further heating, the metastable Fe 3 B phase is transformed into the stable Fe 2 B phase. The highest content of the Fe 3 B phase is observed in the Fe 75 Ni 2 Si 8 B 13 C 2 alloy (Figure 3), which could be a consequence of the presence of a suitable amount of Ni in the alloy, since it is considered that the Ni element present in an appropriate amount can retard the degradation of metastable boride phases [38]. In the case of the Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 alloy, the Fe 3 B phase can be observed only in very low amounts (few wt. % of crystalline phases) (Figure 3c) [18]. Actually, at higher temperatures, the crystalline phase with body centered cubic structure (α-(Fe,Ni)) is destabilized by high Ni content. Application of TEM method confirms the results of XRD analysis and Mössbauer spectroscopy in terms of crystalline phases formed during heating [18,20], showing that, after heating at the highest temperatures, the alloy structure is composed of grains, several 10s to several 100s of nanometers in size and irregular in shape, which are formed by coalescence of neighboring grains and influenced by impingement (Figure 4) [19][20][21]. Crystallization changes the morphology of the alloy sample and the distribution of individual elements on the surface of a sample [19,20], which, after formation of crystalline phases, becomes nonuniform. As a result of crystallization, the alloy structure is more porous, because of imperfect packing of the crystals (Figure 4b) [17,20,26]. Surface morphology depends significantly on the heating rate and the temperature up to which the sample was heated, in other words on thermal history of a sample [19].
The thermal treatment causes continuous growth of the average crystallite size of α-Fe(Si) and Fe 2 B phases in the alloys containing Fe as the dominant metal component except for the Fe 73,5 Cu 1 Nb 3 Si 15,5 B 7 alloy, according to the XRD analysis ( Figure 5). However, it can be observed that the average crystallite size of α-Fe(Si) phase in the Fe 73,5 Cu 1 Nb 3 Si 15,5 B 7 alloy remains the same, around 15 nm, over a wide temperature range. This is expected as a consequence of the presence of Nb atoms in the amorphous matrix, which, due to their large atomic radius, hinder the diffusion of Fe and Si to the crystal, obstructing its further growth [14]. When crystallization of the phase containing Nb starts, further crystal growth of α-Fe(Si) phase occurs.
For all the alloys examined, the average crystallite size of the α-Fe(Si) phase at the highest temperatures amounts to 80-100 nm, except for the Fe 79,8 Ni 1,5 Si 5 ,2 B 13 C 0,5 alloy, where it is around 35 nm. This exception can originate from the crystallization kinetics of individual steps of formation of α-Fe(Si) phase in this alloy, where a higher ratio of the nucleation rate to the crystal growth rate than in the other alloys examined occurs. On the other hand, when it comes to another phase observed in all the alloys containing Fe as the dominant component, Fe 2 B, its crystallite size reaches approximately 50 nm after heating at the highest temperatures, except for the Fe 73,5 Cu 1 Nb 3 Si 15,5 B 7 alloy, where the size of around 30 nm is contributed by lower boron content in the alloy. In the case of the alloy containing 40 atomic % of iron, in accordance with the chemical composition and unique phase compositions, during thermal treatment, the average crystallite size of the formed phases changes slightly in temperature ranges in which nucleation is the dominant process or exhibits more pronounced changes in temperature intervals where the crystal growth dominates [18].

Influence of thermal treatment on functional properties
Functional properties of the as-prepared and thermally treated amorphous alloys are significantly influenced by their microstructure beside the chemical composition. In the case of very low thermal effects, thermally induced microstructural transformations are more noticeable in the changes of functional properties than by thermal analysis. Bearing this in mind as well as potential practical application of the studied alloys, microhardness, thermomagnetic resistivity, and electrical resistivity analyses were performed.

Microhardness
In the as-prepared form, the examined alloys exhibit relatively high microhardness values, over 900 HV [20,26,30], as shown for the Fe 73.5 Cu 1 Nb 3 Si 15.5 B 7 , Fe 75 Ni 2 Si 8 B 13 C 2 , and Fe 81 B 13 Si 4 C 2 alloys (Figure 6a). Thermally induced formation of nanocrystalline structure results in an increase in the microhardness value, which reaches maximum at around 500-600°C and then declines (Figure 6a). The  maximal microhardness values correspond to the optimal microstructure, consisting of a composite involving nanocrystals embedded in amorphous matrix. This structure has a lower interfacial energy than purely amorphous or purely crystalline structure with crystal/crystal interface, suppressing propagation of shear bands and cracks along the interfaces [20,26,30]. At higher temperatures of thermal treatment, the dominant crystal/crystal interface with higher interfacial energy leads to easier shear band and crack propagation, yielding lower microhardness values.

Thermomagnetic measurements
Thermomagnetic measurements on heating [18,20,25,28] revealed thermally induced microstructural changes, influencing the magnetic properties of the alloys. All the studied alloys exhibit two Curie temperatures (Figure 7), one corresponding to the as-prepared alloy (T c1 ) and the second one corresponding to the Curie temperature of the alloy in the crystallized form (T c2 ) ( Table 1). The alloys   It is well known that the addition of Nb reduces the Curie temperature of the amorphous phase by around 25% per atomic percent of Nb, while the influence of Cu is negligible [39]. Relatively low Fe content, relatively high Ni content, and the presence of P in the amorphous Fe 40 Ni 40 P 14 B 6 alloy result in low value of the Curie temperature of this alloy. This is a consequence of the facts that Ni has lower Curie temperature and lower magnetic moment than Fe and the P addition has a decreasing effect on magnetic moment [40].
The beginning of crystallization process (Figure 7), as a result of formation of various magnetic crystalline phases, leads to an increase in magnetic moment of polycrystalline alloys. The manner of magnetic moment growth during the crystallization and subsequent decline when approaching the T c2 are determined by phase compositions of individual crystallized alloys. Thus, for example, in the case of Fe 73.5 Cu 1 Nb 3 Si 15.5 B 7 , a rise in magnetic moment can be observed up to around 550°C, and then its drop starts, moving toward the Curie temperature of the formed crystalline phases. It should be noted that for the FINEMET-type alloys, to which Fe 73.5 Cu 1 Nb 3 Si 15.5 B 7 belongs, literature data [3,41] usually include only the second value of Curie temperature because of its importance for practical application, since these alloys are mostly used in nanocrystalline form obtained by partial crystallization of amorphous precursor. Similarity of the T c2 values of the Fe 75 Ni 2 Si 8 B 13 C 2 and Fe 81 B 13 Si 4 C 2 alloys results from their very similar phase composition in the fully crystalline form. However, the lowest T c2 value was observed for the Fe 40 Ni 40 P 14 B 6 alloy, because the phases γ-(Fe,Ni) and (Fe,Ni) 3 (P,B) which constitute fully crystalline alloy are characterized by lower Curie temperature values than the α-Fe(Si) and Fe 2 B phases forming the alloys with Fe as the dominant component.

Electrical resistivity measurements
Electrical resistivity measurements performed on the alloys containing 73-81 atomic % of iron [15,27,29,42], at room temperature, reveal that the as-prepared Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 and Fe 81 B 13 Si 4 C 2 alloys exhibit slightly lower electrical resistivity values, and better electronic conductivity, than the Fe 73.5 Cu 1 Nb 3 Si 15.5 B 7 and Fe 75 Ni 2 Si 8 B 13 C 2 alloys (Table 3), which is attributed to their somewhat higher iron content. As expected, after heating at different temperatures, each structural transformation is followed by certain changes in the trend of temperature dependence of electrical resistivity [15,27,29,42].   Table 3.
Electrical resistivity of the as-prepared alloys containing 73-81 atomic % of iron at room temperature.
The influence of thermally induced structural transformations on electrical resistivity of amorphous alloy can be illustrated with the example of Fe 75 Ni 2 Si 8 B 13 C 2 alloys [27]. In the temperature range 20-500°C, thermal treatment causes an increase in electrical resistivity (Table 4), where the slightly faster growth in the region 250-400°C corresponds to the structural relaxation, while the sharp increase occurs near the Curie point (400-430°C) [27]. Crystallization process, which starts at around 500°C, involves the sudden decline in electrical resistivity, since the ordered structure possesses lower electrical resistivity than the amorphous one. The second heating of the crystallized alloy results in linear growth of electrical resistivity with temperature [27], which is typical behavior of electronic (metal) conductors.
Measurement of electrical resistivity of the Fe 81 B 13 Si 4 C 2 alloy after thermal treatment represents a good example of the situation when the functional properties are more sensitive to microstructural changes than thermal analysis. Derivative curve of the temperature dependence of electrical resistivity exhibits two well-defined maxima in the crystallization region (Figure 6b) [29], indicating that the crystallization in this case is a multistep process, although it occurs as a single peak in the DSC curve.

Crystallization kinetics
The knowledge of crystallization kinetics, besides thermal stability, is very important for usage of these alloys in modern technology, in order to estimate their applicability. The increase in heating rate leads to a shift in DSC peak temperature toward the region of higher temperatures [19,[21][22][23][24], showing that the observed processes are thermally activated, allowing the application of Arrhenius equation for kinetic description of the examined processes.
The kinetics of single-step solid-state phase transformation can be described using the equation: where T is the temperature, R is the gas constant, α is the conversion degree, β is the heating rate, f(α) is the conversion function representing the kinetic model, E a is the activation energy, and A is the pre-exponential factor. The two last mentioned parameters are Arrhenius parameters, while the set including E a , A and f(α) represents the kinetic triplet. For full kinetic description of a process, determination of kinetic triplet is required. Practical significance of kinetic triplets is determination of material lifetimes related to structural stability of materials and process rates [43].
Most of the observed crystallization DSC peaks are asymmetric as a result of complexity of crystallization processes involving more than one crystallization step. In order to study the kinetics of individual steps, complex crystallization peak deconvolution by application of appropriate mathematical procedure [19,[21][22][23][24] is required. For confirmation of single-step processes, isoconversional methods [43][44][45][46][47][48][49] are used.
Crystallization apparent activation energies for the formation of individual phases in the examined amorphous alloys, determined using Kissinger method [44], are presented in Table 5. The values obtained for the α-Fe(Si) phase are in the range 300-400 kJ/mol, while 200-350 kJ/mol are those determined for the Fe 2 B phase. For all the crystalline phases in all the alloys examined, relatively high E a values are obtained, probably as a result of cooperative participation of a large number of atoms in each step of the transformations [36]. The E a values, obtained best describes the kinetics of crystallization, for all crystallization steps [19,[21][22][23][24]. Conversion functions of individual crystallization steps, in different alloys, are presented in Table 5. By introducing the kinetic triplets of individual crystallization steps into the equation for the solid-state transformation rate, with corresponding normalization and summation, simulated DSC curves can be obtained, which are, for the studied processes, in full accordance with experimental DSC curves [19,21,23], confirming the validity of the obtained kinetic triplets (Figure 8).
More information on crystallization mechanism can be obtained by considering values of local Avrami exponent, n [53]. Local Avrami exponent as well as the manner of its change with the progress of the process can indicate a certain transformation mechanism. For all crystallization steps of the examined alloys, decline in n value with the progress of transformation is observed (Figure 9) [19,21]. This suggests the occurrence of impingement during the crystal growth, which was also indicated by microstructural analysis, as mentioned previously [19][20][21]. For non-isothermal measurements, at constant heating rates, conversion degree which corresponds to the position of the transformation rate maximum (α p ) suggests the anisotropic crystal growth as the prevailing type of impingement [54]. This includes blocking effects of growing particles occurring earlier than those for the isotropic growth, leading to hard impingement and to deviation from the classical JMA model [54]. Anisotropic crystal growth was also suggested by the existence of preferential orientation [17].
After determining the kinetic triplets, the lifetime of the alloys against crystallization which reflects their thermal stability as well as the stability of their functional properties is estimated. For the conversion degree of 5%, at room temperature, the alloys exhibit high lifetime values (10 27 -10 39 years) ( Table 6), indicating that these materials are very stable at room temperature, in spite of their thermodynamic and kinetic metastability [21,23]. Nevertheless, an increase in the  temperature of thermal treatment leads to an exponential decline in the values of estimated lifetime against crystallization, which amounts to only several minutes at the temperature of the onset of crystallization process [21,23]. At room temperature, the amorphous Fe 79.8 Ni 1.5 Si 5.2 B 13 C 0.5 alloy shows lifetime value by several orders of magnitude higher than those of the other alloys containing 73-81 atomic % of Fe, which is in accordance with its higher thermal stability. In spite of crystallizing at lower temperatures than the alloys with 73-81 atomic % of Fe, the alloy containing 40 atomic % of Fe shows higher thermal stability at room temperature, manifested by higher lifetime values than those of the alloys containing Fe as the dominant component ( Table 6).    Table 6. Estimated values of the lifetime of the alloys against crystallization at room temperature, determined for conversion degree of 5%.